Reduction of 4-t-Butylcyclohexanone
. side of the molecule gives trans-4-t-butylcyclohexanol as the major product, . stabilities of the two products and note that the cis isomer has greater steric . From the Adjust menu select the Dihedral Angle option and enter the value of zero.
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1.41 T. ?E = ?h/2?(Bo). Rf Field vs. Magnetic Field for a Proton. Rf Field . Dependence of J on the Dihedral Angle. The Karplus Equation. 1H NMR (400 MHz): cis-4-t-Butylcyclohexanol . 1H NMR (400 MHz): trans-4-t- Butylcyclohexanol .